Now, I have been using Ganondorf against my brother lately, and he cannot seem to beat me. We think we know why, and we think it puts Ganon at the top of the tiers. I will be brief.
Ganondorf has his air forward. We call it 'The Punch.' It has that special hitbox like a sword, hence it goes right through anything except an attack with that same type of hitbox. It does 17% max, is relatively fast executing, has basically instant recovery on a barrier cancel, and is quite massive, killing at rather low percentages.
If he misses, he can just do his A punch if the opponent tries to retaliate, or shield/roll. I am telling you, Ganondorf is a crazy meat mountain who crushes bones with many attacks doing 15+%, survives to insane damages thanks to his weight, and has ridiculous horizontal recovery (Double Jump, Ganondorf Kick Down B, ANOTHER Double Jump, ARE YOU SERIOUS, Up B).
Next, check his roll. It goes like half screen. It makes him rather fast, nearly eliminating his speed problem on the ground, and a great character when it comes to the defensive game. It pretty much eliminates the need for his wavedash, which, with Ganondorf, who needs to do most of his attacking from hops, is pretty much useless already unless you are looking to smash attack. Wavesmashing, however, in my opinion, is also a bad idea, because, in the time and damage it takes you to actually land a smash, you could have just used The Punch and killed you opponent by then.
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Sounds scary. :o