PoE has better armor and the Trials weapons are better only because they have a burn on them. Might I add that burn weapons can drop from Skolas.
The best PvE weapons or weapons in general drop from The Vault of Glass.
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I have most of the weapons from the game I'm just pissed at the fact that the PVP players get rewarded better. They get another location to visit and get a load of gear to choose from and we get crap all in all I'm just a little bitter at being shafted again and again in this game yet I keep coming back for more. Cheers