My absolute favourite would be Lelouch from Code Geass. Though a list of my top 10 would look like this:
1. [url=http://myanimelist.net/character/417/Lamperouge_Lelouch]Lelouch[/url] (Code Geass)
2. [url=http://myanimelist.net/character/498/Tohsaka_Rin]Rin Tohsaka[/url] (Fate/Stay Night)
3. [url=http://myanimelist.net/character/2257/Simon]Simon[/url] (Gurren Lagann)
4. [url=http://myanimelist.net/character/22052/Hachikuji_Mayoi]Mayoi Hachikuji[/url] (Monogatari)
5. [url=http://myanimelist.net/character/2087/Archer]Archer[/url] (Fate/Stay Night)
6. [url=http://myanimelist.net/character/63845/Kirigiri_Kyouko]Kyouko Kirigiri[/url] (Danganronpa)
7. [url=http://myanimelist.net/character/4605/Fujibayashi_Kyou]Kyou Fujibayashi[/url] (Clannad)
8. [url=http://myanimelist.net/character/35252/Okabe_Rintarou]Rintarou Okabe[/url] (Steins;Gate)
9. [url=http://myanimelist.net/character/558/Stadtfeld_Kallen]Kallen Stadtfeld[/url] (Code Geass)
10. [url=http://myanimelist.net/character/63971/Hambart_Hampnie]Hampnie Hambart[/url] (Kamisama no Inai Nichiyoubi)
So, what about you guys?
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I'm going to try and stick to one per show otherwise I'll get carried away with some of my favourites <.< Obviously links to character wikis might contain spoilers :P 1. [url=http://clannad.wikia.com/wiki/Akio_Furukawa]Akio Furukawa[/url] (Clannad) 2. [url=http://lagooncompany.wikia.com/wiki/Balalaika]Balalaika[/url] (Black Lagoon) 3. [url=http://en.wikipedia.org/wiki/L_%28Death_Note%29]L/Ryuzaki[/url] (Death Note) 4. [url=http://angelbeats.wikia.com/wiki/Kanade_Tachibana]Angel/Kanade[/url] (Angel Beats) 5. [url=http://angelbeats.wikia.com/wiki/Shiina]Shiina[/url] (Angel Beats, I know I said one per show but AB is my favourite <.<) 6. [url=http://myanimelist.net/character/2773/Altera_Birdy_Cephon]Birdy Cephon Altera[/url] (Birdy the Mighty) 7. [url=http://shingekinokyojin.wikia.com/wiki/Levi]Levi[/url] (Shingeki no Kyojin) 8. [url=http://angelbeats.wikia.com/wiki/Yuri_Nakamura]Yurippe[/url] (Angel Beats. Don't judge me D:) 9. [url=http://luckystar.wikia.com/wiki/Konata_Izumi]Konata[/url] (Lucky Star) 10. [url=http://1.bp.blogspot.com/-kLLEldYSICM/UQp3scQEmnI/AAAAAAAAAIE/WB-d2Q_4rwk/s1600/SUy3l.png]Revy[/url] (Black Lagoon, I gave up on the no doubles rule <.<)