I want to buy the dlc but don't know which platform to buy for and thought if I buy them through Microsoft store on Xbox I could access them on pc If I downloaded it from Microsoft store
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For XBox/Microsoft Store games to be purchased once, playable on both platforms it must have the Play Anywhere logo on its store page. Currently none of the Destiny 2 content is marked as Play Anywhere, so no, purchasing DLC on the XBox Store will not unlock that content for you on the Microsoft Store version. However, if you subscribe to Gamepass Ultimate that gives you Gamepass for XBox and Gamepass for PC and both Gamepass versions include D2 DLC content up to Beyond Light.
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I'm not sure if you purchase them on XBOX, but I would think that it would work. I know that if you have the game pass ultimate, which gives you all the big DLC's, you can download it on both the XBOX and Microsoft PC ports.