I would say that just because someone's a phenomenal PvP player doesn't mean they're a phenomenal PvE player.
They require different mindsets. They require you to understand how your build works in different ways. There's also different strategies of how to use teamwork in PvE.
Something I would personally love to see is a phenomenal PvP player and PvE player starting a solo Shattered Throne run at the same time and see how they both perform/builds that they use for each part. That's actually a stream that I would watch.
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Well sure, that's fair. And I'm not talking about people that exclusively play pvp either. They might have the raw skill but not the knowledge of when to super, when to use heavy, etc. But most players I know play both pvp and pve. And the ones who are really good at pvp are also really good at pve. My point was, pvp is harder to get kills so it forces you to get good, which builds upon whatever pve skill you already had. Or something like that...