Only if you roll Sureshot, Rangefinder, Rifled Barrel and Hidden Hand. It has a base stability of 42. It also has a base aim assist at 81. With Sureshot and hidden hand, it will be right at 100. Rangefinder and Rifled Barrel will help with the 25 base range stat. So to simplify it, within hand cannon range, it will hit your target as long as you're aimed near it. So head shots will come very easy.