The thermite grenade is one of the more tactical grenades in the game(and is -blam!-ing awesome in pve) and the sunstrike is extremely useful as it burns your enemies health or when paired with cauterize you regen your health on a kill. Not to mention this is obviously handy in cqc in pve but also has proven to be quite handy in pvp for me thus far.
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It is fun just to clear a hallway in PvP or a line of Thrall in PvE with one thermite grenade. If only the Armamentarium were a year two exotic