I can buy 2 armor pieces from him but I have an exotic chest and everything else is rare. What should I do
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Dead Orbit aye? Welcome to the family!
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Get legs an arms, run a 32 PoE and use the armour core to get 42 light helm from variks
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If you take a look at each faction they all have different statistic increases. I think this link may help you understand the benefits the different factions can provide. If you're dead set on Dead Orbit equipment then I would suggest gauntlets and leg armor.
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Dump Dead Orbit and join the Cult. It's the only way.
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Boots and pants
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Boots and gloves