But the problem with the headshot kills perk is that it is now nearly impossible, since it is not a one hit kill. It don't think it counts if the burn kills them and not the headshot, but I'm not sure. Which renders that perk useless.
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The reset cool down on a headshot perk is designed for PvE mobs, not PvP. You should be running Incendiary Knife in PvP if you want to be the most effective Hunter you can. Softening up a target or ensuring a post mortem kill trade with the flaming knife is more important than MAYBE getting your cool down reset if you nail am already damaged target with a knife headshot.
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I don't use burn, I use headshot reset. The perk is generally useless in PvP but I have gotten three throwing knife kills in one life once.