Since you have your PSN characters as the Active set for Cross Save, you can unlink the current Steam account and link your desired Steam account as long as you can authenticate the account. Note that accounts cannot be unlinked while Cross Save is active, and de-activating Cross Save initiates a 90-day cooldown that prevents Cross Save from being reactivated for security reasons.
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so once i unlink i seriously have to wait for 90 days to be able to play? is there any way i can bypass that with like some authentication thing?
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Yup, super cereal. The cooldown is in place for security reasons.