Seriously, I can't get enough of it. It is so satisfying to use. I'll burst out in laughter after going through an entire mob with just throwing knives. I have the perk on my Hunter that I have two throwing knives and if I get a critical kill with it, it automatically resets the cool down.
So sound off all you hunters that enjoy the throwing knife!
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I use it as another tool in the Gunslinger kit. Usually I try to use it as often as I can to conserve ammo. I also use the talent that automatically resets the cooldown on crit damage. Usually works out pretty well, if I'm careful with my aim I can get some pretty nice strings of knife tricks going. I hate to switch to the two knife talent because Chain of Woe is just that good.