I've been playing on my Titan all day and he has only had 1 prime engram pop for him. Prime Attunement is still active for him. Is there a solution for this or am I just out of luck?
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As long as Prime Attunement is active, all stronger-classed enemies have a chance to drop a Prime Engram. It's up to RNG. Sometimes you might get one after only a kill or two, and sometimes it may take several hours of killing them.
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Out of luck unless you grind like crazy. Or you could be me. I just grinded for hours to get the final prime I needed and it dropped as an exotic which meant it didn't count towards the bounty!
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Primes are once a day unless you have a backlog of them from missed days.