I let my post master overflow and just lost 9 ascendant shards and 4 alloys, it's ridiculous that I couldn't have just moved them to the vault in the first place or had just been allowed to carry more! What is the point of this Bungie?!
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I feel for you. Remember that DIM has farming mode so you can prevent things going to post master. I know this is hard but I had a similar problem a few seasons ago- you just have to make a build and decide in advance what you will do with the ascendant shards. You can also MW an exotic for 3 shards and get back 1- so worst case scenario that is how you can store shards in the vault.