The Hive Splinter weapon will not charge the Unbreakable aspect and related effects (Ursa Furiosa/Spirit of the Bear) when hitting its Void shield.
I tested in Gambit (Elite Acolyte), the Pale Heart (Hive Barrier Champion), the Throne World (Lightbearer Acolyte) and nothing changed.
Happens with all grenades available on Prismatic and Sentinel.
The projectile hitting the player directly (point blank or from behind) will charge the ability correctly.
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Hi there, Thanks for reaching out! We'll pass this along to developers for further investigation.