I always turn in the dailys as i do them, and i always focus on only 1 character
As soon as you have 1 at rank 5 the other 2 get an extra 100% boost to rank that stacks with the other daily boost and emblem/shader/class item boosts
I usually start with the last one I brought to 5, that one always has the most completed bountys
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Sounds like a good easy to do it