Smoke is fantastic for stunning enemies, especially with poison. The vanish in smoke is also really useful.
As for the super I recommend either black hole or quiver, depending on personal preference. I also recommend getting the perk that doubles the effects of smoke and grenade effects.
As for your grenade, voidwall is useful, but so are each of the grenades so just find the one that you like.
Other than that, keen scout and or shadestep are a must. I recommend the helmet that grants shadestep so you can have both.
Experiment with these and find the setup that you like. Hope this helps.
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I love the smoke as I can actually get kills. With every other character I use exclusively intellect and discipline (except sunsinger) but with the void bow the grenades are all so useless. I use the tether that lasts longer and has extended range. Very powerful for control and area domination maps. I just wish the grenades weren't as powerful as wet noodles. Getting twenty void grenade kills is so annoying.......
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It's really not too difficult. You have to use the grenades for territory control for the best effect though. I personally prefer voidwall for trapping enemies against walls or in corners. People tend to ignore the purple fire for what ever reason as well.
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I would love it if it were more controllable. The direction is always so random. When you want it to zig it zags..... I find myself going back to vortex grenades because at least they are consistent. Now I'm doubting wether to even use the grenades - the smoke is somewhat effective!