The bounty (TITAN) does not show up when Xander 99-40 redemption panel opens.
Seems to be a glitch
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What do you mean by Titan? As in your character is a Titan?
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Do you have by any chance some exotic bounties active? You can only every bounty active once. You can't have the same bounty twice. If you have the three bounties active that the Vanguard Mentor Missive would provide, if will show up that the Missive does not grant any bounties.
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This belongs under feedback, but thanks for the observation!