Hey, I have been wanting to buy the game again for PC as I did quit playing on Xbox right before the Osiris DLC came out. I spent 90$ on the edition for Xbox and never thought I would be getting a PC and I have been watching lots of gameplay on the new DLC and it looks like so much fun that I would love to get some action on. My biggest issue right now is me loosing all of my loot from the console and all those items I can't get any more. I am perfectly keen on buying the game again including DLC.
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You will have to start over. All your characters and loot are tied to your Xbox account. There is no way to transfer it over.