Hi.
I recently used a [i]Heavy Ammo Synthesis[/i] while in orbit, since I knew I would need it when on the ground.
One item was consumed and the cooldown timer started, but when I landed I had no new ammo. I went back into inventory and the timer was still going and the item was missing, but no ammo.
Bug?
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Yea heavy ammo synthesis wont refill if your inventory is full, is just a coincidence that didnt refill you while on orbit... If indeed your inventory is full, store some stuff in yout vault cause its a well known issue