Since the dark bellow I've noticed that sometimes when I use a synthesis it doesn't ad any ammo but it does get the timer.
Just pointing it out.
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You need to have one open spot in your inv. It's a long time bug. Just put some stuff in the vault.
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Sometimes I've heard, from multiple people, that when your inventory is full (when you have full inventory where you carry your heavy/special ammo synths) it won't work. Don't know why but it has happened to me before as well so I know what you're talking about, and what I mentioned above seemed to be the issue. Hope this helps!
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Will xbox get undyingmind?
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Sane happens to me with both specials and heavy synths.
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Is your consumables full?
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And I'm not the only one who experienced it.