Purely cosmetic.
The only ones that affect anything are the ones you buy from the factions. They re-route all your earned Crucible and Vanguard rep to the faction you're representing with a mark/bond/cloak.
Kinda' silly, yep. It'd be cool if they came with some stats or perks that were helpful to the appropriate class. I have found some that look pretty cool though, so... keep looking. Definitely not the best place to be spending any kind of currency though. :-)
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Just what I thought =C Sucks everything makes you hold a button or press it twice, then I press the wrong button once, and poof: there goes 65 crucible marks!
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Mega ouch. Sorry, dude.