I had about 120+ Strange Coins. When Xur came out this weekend I decided to buy tons of Heavy Ammo Synthesis because I don't have the Glimmer for it. I've stored about 100+ Heavy Ammo Synthesis in my Vault and about a 100 each on 1 of my characters. Everytime i use a Heavy Ammo Synthesis it doesn't refill my Heavy Ammo. I've used over 10 so far and it hasn't work. I've used it on Patrol, Strikes, Ect... Please help.
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I'm having the same problem.
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It's a bug that happens when your inventory is completely full, just make sure you have one open slot.